dc.contributor.author | Hiromichi, Aono | |
dc.contributor.author | Muhammad Asri, Idris, Dr. | |
dc.contributor.author | Yoshihiko, Sadaoka | |
dc.date.accessioned | 2014-06-08T04:47:15Z | |
dc.date.available | 2014-06-08T04:47:15Z | |
dc.date.issued | 2004 | |
dc.identifier.citation | Solid State Ionics, vol.166(1–2), 2004, pages 53–59 | en_US |
dc.identifier.issn | 0167-2738 | |
dc.identifier.uri | http://www.sciencedirect.com/science/article/pii/S0167273803005216 | |
dc.identifier.uri | http://dspace.unimap.edu.my:80/dspace/handle/123456789/35187 | |
dc.description | Link to publisher's homepage at http://www.sciencedirect.com/ | en_US |
dc.description.abstract | The monoclinic phase (P21/n) was formed for 0≤x≤0.6 and the NASICON-type rhombohedral phase (R3̄c) was obtained for the region 0.8≤x≤1.2 in the Li3−2xCr2−xTax(PO4)3 system. The activation energy for Li+migration was ca. 0.45 eV for the monoclinic structure and ca. 0.36 eV for the rhombohedral structure. The maximum conductivity of 8.4×10−6 S cm−1 at 298 K was obtained for x=0.8 of the Li3−2xCr2−xTax(PO4)3system. The conductivity of LiCrTa(PO4)3 was enhanced about three to five times by the addition of the lithium salt due to the improvement of the sinterablity. The maximum conductivity was 2.4×10−5 S cm−1 at 298 K for LiCrTa(PO4)3–0.2Li3BO3. | en_US |
dc.language.iso | en | en_US |
dc.publisher | Elsevier | en_US |
dc.subject | Li+ ionic conductor | en_US |
dc.subject | Solid electrolyte | en_US |
dc.subject | LiCrTa(PO4)3 | en_US |
dc.subject | NASICON | en_US |
dc.subject | Conductivity | en_US |
dc.title | Ionic conductivity and crystal structure for the Li3−2xCr2−xTax(PO4)3 system | en_US |
dc.type | Article | en_US |
dc.identifier.url | 10.1016/j.ssi.2003.11.005 | |
dc.contributor.url | asri@unimap.edu.my | en_US |